Journal of Liaoning Petrochemical University
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Effect of Relative Molecular Weight of MAM on the Structure and Properties of PLA/PBAT/MAM Blends
Haifeng ZHANG, Guixin ZHANG, Yuexin HU, Xiangyan HAN, Yuanyuan HAN, Guiyan ZHAO
Abstract463)   HTML13)    PDF (1006KB)(70)      

Polylactic acid/Poly(butylene adipate?co?terephthalate)/Poly(methyl methacrylate)?b?poly (butyl acrylate)?b?poly (methyl methacrylate)ternary blends (PLA/PBAT/MAM) were prepared by melt blending, and the effect of MAM relative molecular weight on the morphology, structure and properties of the blends was investigated. The results showed that the addition of MAM block copolymer can inhibits the crystallization of PLA,improve the compatibility of PLA/PBAT, reduce the particle size of the dispersed phase and make the distribution more uniform, improve the impact properties and elongation at break of the blends. And the relative molecular weight of MAM increased, the impact strength and elongation at break of the blend increased, the smaller the size of the dispersed phase particles, and the more uniform of particle size distribution.

2024, 44 (1): 9-14. DOI: 10.12422/j.issn.1672-6952.2024.01.002
Synthesis of Citric Acid Type Deep Eutectic Solvent and Its Application in Oxidative Desulfurization
Qinggong MENG, Xinyi ZHU, Chensheng CHANG, Yanhui LI, Yuhang ZHU, Yan ZHAO, Xiuping LI, Rongxiang ZHAO
Abstract149)   HTML14)    PDF (1009KB)(139)      

Citric acid type deep eutectic solvent was synthesized using citric acid(CA) and choline chloride (ChCl) as raw materials. The existence of hydrogen bonding in deep eutectic solvents (DESs) was determined by infrared spectrum and hydrogen spectra. Sulfide in simulated oil was removed using DESs as extractant and potassium bisulfate as oxidant. The effects of the amount of water, the amount of oxidant, the ratio of hydrogen bond donor and acceptor, reaction temperature and different sulfides on desulfurization rate were investigated, and the optimum reaction conditions were determined. The results showed that the removal rate of DBT in simulated oil was 98.50% at V(model oil)=5 mL, n(ChCl)/n(CA)=1.0∶0.5, V(DES)=2.0 mL, T=30 ℃, m(catalyst)=0.6 g, m(water)=0.4 g. After five times of recycling, the desulfurization rate remains above 95.00%.

2023, 43 (5): 14-19. DOI: 10.12422/j.issn.1672-6952.2023.05.003
Dynamic Mechanical Properties and Constitutive Model of Double Phase Steel HC420/780DP
Zhentong Dong, Xianming Meng, Jianjun Guan, Yan Zhao
Abstract785)   HTML14)    PDF (1683KB)(958)      

High?speed tensile tests of HC420/780DP dual?phase steel at strain rates of 0.001,0.100,1.000,10.000,100.000 s-1 and 200.000 s-1 were carried out. The dynamic mechanical behavior of the materials under different strain rates was studied. The true stress?strain curves of HC420/780DP at different strain rates were obtained, and the fracture elongation, tensile strength and flow stress were analyzed. The results show that the flow stress, yield strength and tensile strength of HC420/780DP dual?phase steel increased with the increasing strain rate. Based on the modified Johnson?Cook constitutive model, the dependent plastic deformation constitutive model versus HC420/780DP dynamic strain rate was established. The fitting results of the optimized constitutive equation are in consistent with the curves of experimental results.

2023, 43 (1): 61-66. DOI: 10.12422/j.issn.1672-6952.2023.01.011
Preparation of Co 9S 8@CNFs Composites and their Application in Lithium⁃Ion Batteries
Jiaqi Zhou, Siran Yang, Feixue Ai, Guiyan Zhao, Yanfeng Bi
Abstract248)   HTML10)    PDF (3248KB)(481)      

Electrospinning is a fiber manufacturing process in which polymers are drawn and spun under the action of a high?voltage electrostatic field. This method has been widely used in material chemistry due to the simple preparation, low cost as well as easily available of micro?nano?scale fibers. In this paper, a polysulfur high?nucleus caged compound (Co48) constructed by thiacalixarene was used as the loading material, and polyacrylonitrile (PAN) and polymethyl methacrylate (PMMA) blend (PAN/PMMA) was used as the spinning support, Co9S8 nanoparticles loaded carbon nanofibers (Co9S8@CNFs) were prepared by electrospinning technique. Composite nanofibers were prepared by spinning carriers with PAN and PMMA mass ratios of 10∶0, 7∶3 and 5∶5, respectively, and the carbon nanofiber composites obtained after heat treatment were used as electrode materials for the study of lithium?ion battery materials. The addition of PAN and PMMA has a positive effect on the electrochemistry of the final product compared to the calcined product of Co48 crystals. The composites fabricated from PAN and PMMA presented high specific capacity,good cycling stability and rate capability.

2022, 42 (6): 21-27. DOI: 10.3969/j.issn.1672-6952.2022.06.004
Research Progress of Conductive Polymer Flexible Strain Sensing Materials
Hua Li, Yutian Zhu, Guiyan Zhao
Abstract393)   HTML    PDF (400KB)(664)      

With the rapid development of human?computer interaction, electronic skin, wearable electronics and other emerging fields, flexible strain sensing materials as one of the core components have become the hot spot of the current research. The conductive polymer composites composed of conductive material and flexible polymer have the advantages of good flexibility, light weight, easy processing and forming, and the conductive property of the material changes under strain stimulus, so it can be used as flexible strain sensing material. This paper reviewed the classification and characteristics of flexible strain sensing materials based on conductive polymer composites, introduced the strain response mechanism of different sensing materials in detail, and summarized the factors that affect the strain sensing performance of conductive polymer composites.

2022, 42 (2): 44-49. DOI: 10.3969/j.issn.1672-6952.2022.02.007